Abstract

In the solvolysis of 4-alkoxy-5-methyl-o-benzoquinone N-arylsulphonylimines (1a) and (1b)(NaOH-MeOH–H2O), the regiospecific attack of MeO– occurs initially on the carbon atom substituted by the alkoxy-group to produce the p-benzoquinone monoacetals (3a) and (3b), respectively.

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