Year-end Sale % OFF 
Abstract
Oligomerization of propylene catalyzed by Cp 2ZrCl 2/ethylaluminoxane or/Et 3Al at low Al/Zr ratios and high temperature regioselectively afforded trimeric carbocyclic products, 1,1,3-trimethylcyclopentane and 1,1,3,4-tetramethylcyclopentane, along with C 6 and C 9 chain olefins. The product distribution was affected by the reaction temperature, the pressure of propylene, the ratio of Al/Zr and the reaction time. The combined selectivity of two five-membered cyclic products attained 61% under the optimized condition. The pathway of regioselective cyclo-trimerization of propylene to substituted cyclopentanes is discussed.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
