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Abstract
A palladium-catalyzed three-component coupling reaction of 2-fluoroallylic acetates with phenols, and imides is disclosed. The reaction was effectively catalyzed by [Pd(C<sub>3</sub>H<sub>5</sub>)Cl]<sub>2</sub>/DPPF in the presence of Cs<sub>2</sub>CO<sub>3</sub>, and phenols and imides were introduced onto the allyl unit through the C–F bond activation. Furthermore, the reaction proceeds with both high regioselectivity and high <i>Z</i>-selectivity.
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