Abstract
The palladium-catalyzed regioselective allylic amination of α-trifluoromethylated allyl acetate occurred using Pd(OAc) 2/DPPE and [Pd(π-allyl)(cod)]BF 4/DPPF. The selective formation of the γ-product was attained by Pd(OAc) 2/DPPE, while the α-product was obtained using [Pd(π-allyl)(cod)]BF 4/DPPF.
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