Abstract
Treatment of Cp*(CO)Fe{kappa2(Si,P)-SiMe2PPh2} with methyl vinyl ketone gave a 1,2-addition product, Cp*(CO)Fe{kappa2(Si,P)-SiMe2OCMe(CH=CH2)PPh2}. A linear-type Cp*(CO)2FeSiMe2PPh2 also reacted with the ketone to yield a 1,4-addition product, Cp*(CO)2Fe{kappa1(Si)-SiMe2OC(Me=CHCH2PPh2}, which was further converted to a seven-membered metallacycle, Cp*(CO)Fe{kappa2(Si,P)-SiMe2OC(Me)=CHCH2PPh2}, upon photolysis.
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