Abstract
The reactions of ▪ with some primary and secondary aliphatic amines affording selective ring opening at C β are reported. The reactions with secondary amines HNR 1R 2 (R 1 = R 2 = Et; R 1 = Bu t, R 2 = CH 2CH 2O(CO)C(CH 3) CH 2; R 1 = Et, R 2 = CH 2CH 2OH; R 1 = R 2 = CH 2CH 2OH) gave the corresponding C 8F 17CH 2 CH(OH) CH 2 NR 1R 2 derivatives. For R 1 = Et, R 2 = CH 2CH 2OH; R 1 = R 2 = CH 2CH 2OH, the reactions proceed through the selective nucleophilic attack of the NH moiety with no evidence of reactivity of the OH group. The reactions with the primary amines, allylamine and n-hexamethylenediamine, gave different products depending on reaction conditions.
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