Abstract
AbstractA regioselective ruthenium‐catalysed strategy for synthesising mono‐, ortho‐sulfonamidated β‐carboline derivatives using sulfonyl azide was accomplished by relying on the intrinsic directing property of β‐carbolines. This protocol is apt for all types of substitutions with compelling yields. We have investigated the reaction mechanism using ESI‐MS by arresting the intermediates associated with this selective transformation. The achieved molecules were also surfaced with potential percentage inhibition against cancer cell lines. In addition, practical and computational analysis on these new scaffolds demonstrated photophysical properties.
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