Abstract
AbstractA highly regioselective hydrogenolysis of the anomeric benzyl group is reported. The reaction involves selective acetolysis of benzyl acetals of various mono‐ and di‐saccharides using 10 % Pd/C under hydrogen atmosphere in the presence of Na2CO3. The generality of the methodology is evaluated by applying it to a number of perbenzylated/orthogonally protected benzyl glycosides.
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