Abstract

High-temperature solutions of the system SrOTiO 2Li 2OB 2O 3 are investigated. The concentration and temperature ranges within which spontaneous crystallization of SrTiO 3 proceeds with component ratios of the solvents of 35:65, 50:50 and 65:35 mol%, respectively, are determined. It is established that with decreasing B 2O 3 content in the solvent, the solubility of SrTiO 3 considerably decreases. It is shown that the region of existence of SrTiO 3 in the phase diagram is in all cases shifted with respect to the stoichiometric composition in the direction of the zone with excess SrO.

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