Abstract
The selective formation of tertiary sp3 centers is possible when allylsilanes 1 are employed as the alkene component in the title reaction. Application of a chiral catalyst system makes the reaction enantioselective. Primarily hetero- and carbo-cycles 2 arise with the catalyst system [Pd2(dba)3/PPh3/Ag2O]; 3 is the main product with Pd(OAc2)/PPh3/NPr4Br/KOAc.
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