Abstract
Donors not required: External hydrogen-bond donors are not required for a highly regio- and enantioselective oxyamination reaction of aldehydes with nitrosobenzene (see scheme). The reaction proceeds in the presence of the structurally simple organocatalyst (−)-(S)-α,α-diphenylprolinol trimethylsilyl ether to afford the oxyaminated compounds in good yields.
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