Regeneration of PAC saturated by bisphenol A in PAC/TiO 2 combined photocatalysis system

Abstract

This study investigated a dual function system combining powdered activated carbon (PAC) and TiO 2 for the removal of trace organics together with the in-situ regeneration of PAC. The combined system with PAC adsorption and TiO 2 photo-oxidation for in-situ regeneration of the PAC was studied as a batch process. Bisphenol A (BPA), an endocrine disrupting compound present at low concentration levels, was used as a model compound. When UV light and 0.5 l min − 1 of oxygen were introduced to the PAC/TiO 2 batch system, the removal of BPA was 2.3 to 3.1 times faster than that of neat TiO 2 oxidation in the pH range of 4 to 10. However, mass transfer of the adsorbed BPA by diffusion from the PAC to oxidation sites on the surface of the TiO 2 was found to be limited because PAC has a strong affinity to adsorb BPA. During in-situ regeneration of PAC by TiO 2 photo-oxidation at pH 7 for 6 h, the removal of BPA from the PAC which was fully saturated with BPA was about 50%. The regeneration of the PAC was improved by increasing the UV-irradiation time (4 h to 12 h) and the light intensity (0.13 mW cm − 2 to 0.425 mW cm − 2 ), but it was not enhanced by increasing temperature, operating at basic conditions, or adding H 2O 2. The results suggest that a process with in-situ regeneration of PAC by TiO 2 oxidation may be feasible.