Refractive index of aerosol particles over the Amazon tropical forest during LBA-EUSTACH 1999

Abstract

Optical properties of aerosol particles were characterized during two field campaigns at a remote rainforest site in Rondônia, Brazil, as part of the project European Studies on Trace Gases and Atmospheric Chemistry, a contribution to the Large-Scale Biosphere-Atmosphere Experiment in Amazonia (LBA-EUSTACH). The measurements included background (wet season), biomass burning (dry season), and transition period conditions. Optical measurements of light scattering and absorption were combined with data on number/size distributions in a new iterative method, which retrieves the effective imaginary refractive index of the particles at a wavelength of 545 nm . For ambient relative humidities lower than 80%, background aerosols exhibited an average refractive index of 1.42−0.006 i. Biomass burning aerosols displayed a much larger imaginary part, with an average refractive index of 1.41−0.013 i. Other climate-relevant parameters were estimated from Mie calculations. These include single-scattering albedos of 0.93±0.03 and 0.90±0.03 (at ambient humidity), asymmetry parameters of 0.63±0.02 and 0.70±0.03, and backscatter ratios of 0.12±0.01 and 0.08±0.01 for background and biomass burning aerosols, respectively.