Refractive Index Dependence of Fluorescence Enhancement in a Nanostructured Plasmonic Grating.

Abstract

Plasmonic gratings are attracting huge interest in the context of realizing sensors based on surface-enhanced fluorescence. The grating features control the plasmonic modes and consequently have a strong effect on the fluorescence response. Within this framework, we focused on the use of a buffer solution flowing across the grating active surface to mimic a real measurement. The refractive index of the surrounding medium is therefore altered, with a consequent modification of the resonance conditions. The result is a shift in the spectral features of the fluorescence emission accompanied by a reshaping of the fluorescence emission in terms of spectral weight and direction.