Reference Correlation of the Thermal Conductivity of Cyclohexane from the Triple Point to 640 K and up to 175 MPa.

Abstract

New, wide-range reference equations for the thermal conductivity of cyclohexane as a function of temperature and density are presented. The equations are based in part upon a body of experimental data that has been critically assessed for internal consistency and for agreement with theory whenever possible. We estimate the uncertainty (at the 95% confidence level) for the thermal conductivity of cyclohexane from the triple point (279.86 K) to 650 K at pressures up to 175 MPa to be 4% for the compressed liquid and supercritical phases. For the low-pressure gas phase (up to 0.1 MPa) over the temperature range 280 K to 680 K, the estimated uncertainty is 2.5%. Uncertainties in the critical region are much larger, since the thermal conductivity approaches infinity at the critical point and is very sensitive to small changes in density.