Abstract
We present and develop alternative catalysts for biomass conversion and specifically lignin conversion into aromatics. Unlike the conventional CoMo and NiMo formulations, our catalysts can convert low-sulfur feedstocks. A set of five magnesia–alumina mixed oxides were screened in the hydrodealkylation of alkyl phenyl ethers as lignin model compounds. The typical selectivity to phenol is 30–75 %. Interestingly, we saw that the more basic the catalyst, the higher the selectivity for phenol. The results concur with the formation of phenoxide (PhO–) and RH3+ fragments on the catalyst surface. These can then react with H+ and H– species formed by the hydrogen dissociation on the MgO surface, giving phenol and hydrocarbons. We conclude that magnesia–alumina mixed oxides are attractive candidates for catalyzing lignin breakdown. These catalysts are highly stable, inexpensive, and readily available.
Highlights
Lignin, the glue that holds trees together, is the most abundant natural resource of aromatic compounds.[1,2,3] In that respect, it is a far more advanced resource than crude oil
We conclude that magnesia–alumina mixed oxides are attractive candidates for catalyzing lignin breakdown
CoMo and NiMo are typically used for catalyzing crude oil hydrodesulfurization (HDS),[14,15] but these refinery catalysts rely on feedstocks with high sulfur content
Summary
The glue that holds trees together, is the most abundant natural resource of aromatic compounds.[1,2,3] In that respect, it is a far more advanced resource than crude oil. This is because lignin already contains aromatic functional groups. CoMo and NiMo are typically used for catalyzing crude oil hydrodesulfurization (HDS),[14,15] but these refinery catalysts rely on feedstocks with high sulfur content. New catalysts are needed for these new feedstocks.[10]
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