Abstract
At pH lower than 5 under conditions of d.c. polarography and cyclic voltammetry the oxime PhCOC(=NOH)CH 3 does not yield the expected reducible α-aminoketone, but rather a non-reducible olefin derivative. Its formation is attributed to a reduction of a diprotonated form of a ketoimine intermediate. In the same pH-range under conditions of controlled potential electrolysis the olefin derivative is slowly converted in a homogeneous reaction into a reducible α-aminoketone.
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