Abstract
The hydrosilylation of isocyanates is promoted by palladium catalysts and affords N-silylformamides or C-silylamides. The orientation of the reaction depended upon the structure of isocyanates. The reaction of carbodiimides with silicon hydrides, catalyzed by PdCl 2 or (Ph 3P) 3RhCl, required higher temperatures to give N-silylformamidines. The adducts obtained in these reactions are precursors to formamides, formamidines, and their N-acetyl derivatives.
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