Abstract
Reduction of five aryltrimethylsilanes and one cyclohexenyltrimethylsilane with lithium in ethylamine gives cyclohexanes in every case. Cleavage of one carbon–silicon bond occurs in 1,3-bis(trimethylsilyl)benzene and 1,3,5-tris(trimethylsilyl)benzene. The stereochemistry of the disubstituted cyclohexanes has been assigned.
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More From: Journal of the Chemical Society, Perkin Transactions 1
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