Abstract

Sensitivity analysis and principal component analysis are applied to the Luo and Epstein (LE) and Edblom, Gyorgyi, Orban, and Epstein (EGOE) mechanisms of the oscillatory Landolt reaction. Once they are reduced to their skeletal structures, these schemes are then compared to an empirical rate law (ERL) model. The routes of positive and negative feedback and the bifurcation structures of the schemes are contrasted. It was found that there was a strong similarity between the EGOE and the ERL models, while the LE model produces nonlinear behavior via a different route

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