Reducing the risk of missing soil contamination by integrating multi-investigated methods in a retired chrome salt factory

Abstract

An effective contamination screening process is essential for mitigating the risk of overlooking pollution during site investigations. While Electrical resistivity tomography (ERT) and portable X-ray Fluorescence (XRF) offer quick assessments of contaminated areas, there is a notable gap in research regarding ERT’s application in the unsaturated soil layer, and portable XRF’s use for screening polluted samples in chromium-contaminated sites. This study gathered soil pollution and electrical resistivity data from a decommissioned chrome salt factory, employing drilling, sampling, XRF, and ERT methods. Predominantly, sulfate and chromium emerged as the pollutants, with concentrations ranging from 19.24 to 12700.00 mg/kg for sulfate, 0.65 to 3000.00 mg/kg for Cr(VI), and 12.00 to 27800.00 mg/kg for total Cr, respectively. Polluted hotspots were identified by lower apparent soil resistivity compared to the background levels at corresponding depth. Notably, a significant inverse correlation was observed between sulfate and Cr(VI) concentration and soil resistivity, particularly with sulfate (R2 =0.48) demonstrated through a power function fit at depths ranging from −4 to 0 m. The XRF analysis for total Cr concentration exhibited a significant correlation (Pearson’s r = 0.67) with chemical analysis, confirming 1000 mg/kg as an effective screening threshold. In light of these findings, this study proposes a scientific procedure that integrates drilling, sampling, ERT, and XRF for soil contamination investigation. This framework aims to support similar site assessments, reducing the risk of overlooking contamination.