Reducing CO2 emissions and improving oil recovery through silica aerogel for heavy oil thermal production

Abstract

Heavy oil reserves comprise more than 60% of global crude oil resources, and thermal oil recovery techniques, especially steam injection, are widely utilized for extracting heavy oil. However, these thermal production processes are characterized by high energy consumption and carbon emissions, which pose significant challenges in reducing CO2 emissions. In response to these challenges, this study presents a novel approach that combines silica aerogel with CO2-assisted thermal recovery technology. Our findings demonstrate that the incorporation of aerogel nanoparticles enhances the adsorption capacity of CO2 in the aqueous phase. The adsorption behavior of CO2 in silica aerogel aligns with the Langmuir model. When silica aerogel nanoparticles are employed in steam flooding, a notable improvement is observed in both oil recovery and CO2 sequestration rate. Molecular dynamics simulations reveal that the porous structure of aerogel enables the adsorption of light saturates molecules from crude oil, promoting their diffusion into the aqueous phase and ultimately enhancing oil recovery. The steam condensation experiments clearly demonstrate that the presence of aerogel and CO2 exerts a substantial influence on the condensation heat transfer of steam, resulting in a reduction in the condensation heat transfer rate between the steam and the cooling wall. Additionally, molecular dynamics simulations reveal that silica aerogel nanoparticles exhibit an affinity for adsorbing onto hydrophobic quartz surfaces, forming an insulating layer between steam and quartz, thereby facilitating CO2 sequestration. The introduction of silica aerogel nanoparticles expands the swept volume of steam heat. This study provides valuable insights into the underlying mechanisms responsible for improved CO2 sequestration and increased oil recovery through the implementation of silica aerogel nanoparticles, offering fresh perspectives on heavy oil recovery.