Abstract
The practical application of lithium-sulfur (Li-S) batteries is impeded by the shuttling of the polysulfide and slow sulfur electrochemical reaction. In this study, a reduced graphene oxide (rGO) wrapped hollow ZnCo layered double hydroxides (ZnCo-LDH) microsphere is fabricated as sulfur host material. The rGO nanosheets offer efficient charge transportation pathways. Meanwhile, the porous rGO and hollow ZnCo-LDH provide sufficient space for sulfur storage and mitigates the volume variation during battery charging and discharging. In addition, ZnCo-LDH exhibits excellent chemical adsorption capacity for polysulfides, and promotes their electrochemical conversion reactions. Benefited from these advantages, the S/ZnCo-LDH@rGO cathode delivers a high rate performance of 796.5 mAh g−1 at 5.0 C, and excellent stability performance with a capacity decay of 0.036 % per cycle after 500 cycles at 1.0 C. This study shows that the porous microsphere design of rGO wrapped layered double hydroxides has excellent application prospects as efficient sulfur host for Li-S batteries.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
