Abstract
Abstract The photosensitization by either [ReBr(bpy)(CO)3] or [Ru(bpy)3]2+ (bpy=2,2′-bipyridine) resulted in the isomerization of 1,1′dibenzyl-1,1′,4,4′-tetrahydro-4,4′-binicotinamide (1) and 1,1′-dibenzyl-1,1′-tetrahydro-4,6′-binicotinamide (2) to give a common mixture of 1, 2, and the diastereoisomer of 2 (3) in a 2:2:1 ratio at a photostationary state, while either direct photoexcitation or thermal activation effected only the isomerization of 2 to 1 but not at all the retro isomerization.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
