Abstract
Very high activities were observed in the redox-induced hydroamination of alkynes by employing a redox-active gold(i) complex featuring an electron-deficient, terphenyl-substituted phosphonite-based ligand. The hydroamination proceeds roughly two-fold faster with the in situ oxidized catalysts than with their reduced form.
Highlights
ISSN 1359-7345 COMMUNICATION Kotaro Satoh, Masami Kamigaito et al Cooperative reduction of various RAFT polymer terminals using hydrosilane and thiol via polarity reversal catalysis
The driving force most often originates from the unsatisfied demand to modify and adjust the properties of phosphine metal complexes, e.g. to face activity, selectivity, or stability issues in the field of homogeneous catalysis
For instance, the well-known biaryl phosphines developed by Buchwald and co-workers (I, Chart 1), which found ubiquitous applications in homogeneous catalysis
Summary
ISSN 1359-7345 COMMUNICATION Kotaro Satoh, Masami Kamigaito et al Cooperative reduction of various RAFT polymer terminals using hydrosilane and thiol via polarity reversal catalysis. Showcasing research from the groups of Jan Paradies from the University of Paderborn and Frank Breher from the Karlsruhe Institute of Technology (KIT).
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