Abstract

A new ruthenium(II) polypyridine complex, [Ru(bpy) 2(PAIDH)] 2+ ( 1) (bpy = 2,2′-bipyridine; PAIDH = 2-pyridyl-1 H-anthra[1,2- d]imidazole-6,11-dione) has been found to display electrochemically “off–on” luminescent switch through exchanging two protons and two electrons between the quinone/hydroquinone redox couple at room temperature.

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