Abstract

1. Redox demercuration of mercury derivatives of 8-alkylquinolines by Pd(0) and Pt(0) complexes affords 5-membered chelate metallocycles, except for the reaction between 8-(α-bromomercuriethyl)quinoline and (Ph3P)3Pt. 2. X-ray structural analysis of the triphenylphosphine-(8-methylquinoline-C,N)palladium bromide molecule has shown that the phosphine ligand is trans-oriented to the nitrogen atom in the Pd coordination sphere.

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