Redox reactions of chromium tetracarbonyl and tricarbonyl complexes: thermodynamic, kinetic, and catalytic aspects of isomerization in the fac/mer-tricarbonyltris(trimethyl phosphite)chromium(1+/0) system

A M Bond,R Colton,J E Kevekordes

doi:10.1021/ic00226a008

Redox reactions of chromium tetracarbonyl and tricarbonyl complexes: thermodynamic, kinetic, and catalytic aspects of isomerization in the fac/mer-tricarbonyltris(trimethyl phosphite)chromium(1+/0) system

A M Bond, R Colton + Show 1 more

https://doi.org/10.1021/ic00226a008

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Journal: Inorganic Chemistry	Publication Date: Mar 1, 1986
Citations: 32

#Trimethyl Phosphite #Tricarbonyl Complexes + Show 8 more

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Abstract

Etudes electrochimiques sur les melanges de cis- et trans- [Cr(CO) 4 P 2 ] +/0 (P=phosphine tertiaire ou phosphite). Identification des especes trans-[Cr(CO) 4 P 2 ] + . Etude de l'isomerisation de fac-[Cr(CO) 3 (P(OMe) 3 ) 3 ]. Parametres d'activation

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