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Abstract
The radical polymerisation of acrylamide initiated with a persulfate/tertiary amine redox pair was performed in liquid (+5 to +35°C) and moderately frozen (–10 to –30°C) aqueous solutions. The reaction in frozen systems resulted in the pronounced increase in the molecular weight of the polymer. The temperature dependence of the yield and molecular weight of cryogenically produced polyacrylamide were of extreme character with a maximum for both parameters in the vicinity of –12.5°C.
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