Redox conditions across the Upper Cambrian of eastern Laurentia: Implications from geochemical proxies

Abstract

The lower part of the Martin Point section (∼ 110 m - rhythmites) spans the uppermost Shallow Bay and lowermost Green Point formations (uppermost Franconian–lowermost Trempealeauan) of the Cow Head Group (western Newfoundland, Canada). It records two post-SPICE (Steptoean Positive Carbon Isotope Excursion) events marked by negative δ13Ccarb excursions (NL1 and NL2) that were also documented in South China. The petrographic and chemical screening of the investigated carbonate samples proves the preservation of at least near-primary geochemical signatures. The proxies of weathering (e.g., Mn, Fe, Al, and ∑REE), bioproductivity (e.g., δ13Corg, TOC, P, Ni, Zn, and Cu), and paleoredox (e.g., Cr, Th/U, Ce/Ce*) have been utilized to reconstruct the paleoenvironmental conditions during the post-SPICE events. The TOC, P, Ni, Cu, Cr, ∑REE, Mn, Fe, and U Ca-normalized profiles exhibit a positive pulse at the base of NL2 (upper negative δ13Ccarb excursion), followed by a drop. This might have resulted from shoaling organic-rich anoxic waters into an oxygenated shallow environment during transgression, which led to a negative shift in the δ13Ccarb and a decrease in TOC contents as well as an increase in the δ13Corg. The correlated enrichment in Zn and δ15Norg values and the Ce/Ce* around unity are consistent with the shoaling scenario. A similar scenario seems to be consistent with NL1 (lower negative δ13Ccarb excursion) although the lower resolution of correlated proxy variations makes the interpretations based on a few points and to be therefore taken with caution.