Abstract

The synthesis of a new class of cross-linkable redox-responsive poly(ferrocenylsilane)-based poly(ionic liquid)s (PFS-PILs) is reported. PFS-PILs self-cross-link at low concentrations into nanogels or form macroscopic hydrogel networks at higher concentrations. PFS-PILs proved to be efficient dispersants in the microemulsion polymerization of methyl methacrylate, producing stable PFS-poly(methyl methacrylate) latex suspensions.

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