Year-end Sale % OFF 
Abstract
The redetermined structure of the title compound, [Mn(C4H5NO4)(H2O)2]n, including the full hydrogen-bonding scheme, is reported; the original report was by Zhang & Lu [Acta Cryst. (2004). E60, m1189–m1190]. The structure contains polymeric chains of MnII cations bridged by iminodiacetate (IDA) dianions. The manganese species assumes a distorted octahedral coordination geometry, formed by two IDA molecules (one tridentate and one monodentate) and two water molecules. The tridentate IDA chelates to the Mn atom in the facial configuration; one chelating five-membered ring is almost planar and the other adopts an envelope configuration. A significant difference of 0.118 (2) A in Mn—Ocarboxyl bond distances is observed within the chelating IDA moiety.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
