Abstract
In comparison with the previous refinement of tetrapotassium di-μ-chlorido-bis[tetrachloridobismuthate(III)] tetrahydrate [Volkova, Udovenko, Levin & Shevchenko (1983). Koord. Khim. 9, 356–360], the current redetermination reveals anisotropic displacement parameters for all non-H atoms, localization of the H atoms, and higher precision of lattice parameters and interatomic distances. The crystal structure is built up of edge-sharing [Bi2Cl10]4− double octahedra with the bridging Cl atoms situated on a mirror plane, three K+ counter-cations (two of which are on mirror planes), and two water molecules that are solely coordinated to the K+ cations. These building units are linked into a three-dimensional network structure. Additional O—H⋯Cl hydrogen bonds between the water molecules and the complex anions stabilize this arrangement.
Highlights
Khim. 9, 356–360], the current redetermination reveals anisotropic displacement parameters for all non-H atoms, localization of the H atoms, and higher precision of lattice parameters and interatomic distances
The crystal structure is built up of edge-sharing [Bi2Cl10]4 double octahedra with the bridging Cl atoms situated on a mirror plane, three K+
Counter-cations, and two water molecules that are solely coordinated to the K+ cations
Summary
Faculté des Sciences de Sfax, Laboratoire de Sciences des Matériaux et d’Environnement, BP 115 Sfax 3052, Tunisia. Symmetry codes: (i) x; y; z þ 1; (ii) x; y 12; z þ 1. The crystal structure is built up of edge-sharing [Bi2Cl10]4 double octahedra with the bridging Cl atoms situated on a mirror plane, three K+. Counter-cations (two of which are on mirror planes), and two water molecules that are solely coordinated to the K+ cations. These building units are linked into a three-dimensional network structure. Additional O—H Cl hydrogen bonds between the water molecules and the complex anions stabilize this arrangement. See: Belkyal et al (1997); Benachenhou et al (1986). See: Larson (1970); Prince (1982); Watkin (1994)
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