Abstract

Bodipy is used for the preparation of Pt(II) bisacetylide complexes which show strong absorption of visible light and long-lived triplet state. Room temperature (RT) near-IR phosphorescence of Bodipy was observed. The π-conjugation framework of visible light-harvesting Bodipy ligand was connected to the Pt(II) center by the C≡C bond. The complexes were used as triplet photosensitizers for triplet-triplet annihilation (TTA) upconversion.

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