Recycling of zinc ions in disc-donut column considering forward mixing mass transfer, and effects of pulsed and non-pulsed condition

Abstract

The current study focuses on the recovery of zinc ions by solvent extraction in the pulsed contactor. The Zn(II) ions from chloride solution were extracted into the organic phase containing di-(2-ethylhexyl) phosphoric acid (D2EHPA) extractant. The resulting data were characterized for the relative amount of (a) pulsed and no-pulsed condition; and (b) flow rate of both phases. Based on the mass balance equations for the column performance description, numerical computations of mass transfer in a disc-donut column were conducted and validated the experimental data for zinc extraction. Four different models, such as plug flow, backflow, axial dispersion, and forward mixing were evaluated in this study. The results showed that the intensification of the process with the pulsed condition increased and achieved higher mass transfer rates. The forward mixing model findings based on the curve fitting approach validated well with the experimental data. The results showed that an increase in pulsation intensity, as well as the phase flow rates, have a positive impact on the performance of the extractor. In contrast, the enhancement of flow rate led to the reduction of the described model parameters for the adverse phase.