Recycling of waste calcium carbonate in lignocellulosic biorefining chain for chiral lactic acid production

Abstract

One of the major end-products of lignocellulosic biorefining chain is the solid residues containing various compounds. The present approach to solid residues treatment is combustion for generation of heat and electricity. This study investigated the potential for recycling of the combustion ash from the solid residues after lignocellulosic dry biorefining process. A range of characterizations showed that the combustion ash contained a high amount of calcium carbonate. By recycling the ash as the neutralizer in biorefining process, the waste calcium carbonate in the ash was efficiently utilized for pretreated biomass neutralization and can replace 40 % of calcium hydroxide for lactic acid production. The chiral L-lactic acid titer reached 102.4 ± 3.6 g/L from 20 % (w/w) solids loading of wheat straw. Three feasible strategies of ash recycling for the investigated biorefinery concept were further proposed base on the rigorous calcium mass calculation, which can efficiently reduce the consumption of neutralizers.