Recycling of marble and granite waste in concrete by incorporating nano alumina

Abstract

This study aims to evaluate the effect of using single and combined marble dust (MD), granite dust (GD) and nano alumina (NA) on the performance of Portland cement concrete. MD and GD were separately replaced by different percentages of cement (2, 4, 6, 8 and 10 wt%). Furthermore, NA was used as addition by different percentages (0.25, 0.5, 0.75, 1.0 and 1.25 wt%) in the individual mixtures. The optimal ratios for MD, GD and NA were used to design two concrete mixtures with combined 6%MD+ 1%NA and 6%GD+ 1%NA. The physical properties (consistency, initial and final setting times), the workability (slump cone test), the mechanical properties (compressive, splitting tensile and flexural strengths) and microstructure analysis (X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM) and Energy-Dispersive X-ray (EDX)) were carried on the single and combined mixtures in addition to control mix. Results revealed a rise in the water quantity needed to achieve standard consistency, along with a reduction in both initial and final setting times, as the content of GD and NA increased. However, in comparison to the control mix, minor effects in the consistency or the setting times was observed when various MD contents were used. Regarding workability, its consistently decreased in all cases in correlation with the surface area of the materials utilized. The highest reduction was observed when employing NA, characterized by the largest surface area, followed by GD, and then MD, which had a marginal effect on workability. For hardened concrete, there was an improvement in strengths of samples with replacing individually MD and GD content up to 6% at all curing ages, followed by a decrease in strengths when the content reached 10% of cement replacement compared to control sample. Concrete mixtures with addition of NA showed significant improvement in strengths at all percentages of addition until reached the maximum increase in strength at 1% then slightly decreased. Concrete with combined (6%MD+1%NA) and (6%GD+1%NA) show significantly improved mechanical properties and compact microstructure enriched with C-S-H in comparison to concrete samples using 6%MD, 6%GD and 1%NA separately.