Recyclable waste Dry-cell batteries derived carbon dots (CDs) for detection of Two-fold metal ions and degradation of BTB dye

Abstract

In modern era, electronic wastes are one of the major threats around us, most of them are reused with less efficiency instead of re-usage, and conversion into valuable products is highly recommended. In this work, we report an innovative approach for the synthesis of highly photoluminescent CDs from waste dry-cell batteries through one-step hydrothermal treatment for the detection and degradation of environmental pollutants. The as-prepared CDs were studied by X-ray photoelectron spectroscopy (XPS), HR-TEM studies, X-ray diffractometer (XRD), Raman spectrometer, FTIR spectroscopy, UV–visible spectrophotometer, and spectrofluorometric measurements. The calculated quantum yield for synthesized CDs was around 13 %. The CDs have uniform particle size distribution, strong photoluminescent behavior, and possess high stability against various environmental conditions. Also, CDs display the selective and sensitive detection of Cr6+ and Co2+ and ions with a detection limit of around 0.11 µM and 0.10 µM respectively. The possible mechanism of CDs was also examined. Moreover, the photocatalytic activity of CDs with Bromothymol Blue (BTB) dye was studied. The degradation efficiency of BTB dye can be achieved at around 84 % over 180 min under the irradiation of direct sunlight in presence of H2O2. To date, it’s the first time we have recycled waste dry-cell batteries into CDs as an effective probe for the detection and decomposition of environmental pollution. Furthermore, this work provides not only an easier route to make good quality and improved photoluminescent CDs from waste material like used batteries and also paves way for the reconversion of global treating waste. Finally, the outstanding detection capability with multiple properties of as-prepared CDs provides various environmental applications like the detection of pollutants and carcinogenic polluted water treatment.