Recyclable nanocellulose-confined palladium nanoparticles with enhanced room-temperature catalytic activity and chemoselectivity

Abstract

We describe the synthesis of even-dispersed palladium nanoparticles (Pd NPs) confined within a cellulose nanofiber (CNF) matrix for developing a high-performance and recyclable catalyst. The CNF matrix was composed of CNF-assembled mesoporous nanosheets and appeared as soft and hydrophilic foam. Ultrafine Pd NPs (∼6 nm) with high-loading (9.6 wt%) were in situ grown on these mesoporous nanosheets, and their dense spatial distributions were likely to generate nano-confinement catalytic effects on the reactants. Consequently, the CNF-confined Pd NPs (CNF-Pd) exhibited an enhanced room-temperature catalytic activity on the model reaction of 4-nitrophenol hydrogenation with a highest rate constant of 8.8×10−3 s−1 and turnover frequency of 2640 h The CNF Pd catalyst possessed good chemical stability and recyclability in aqueous media which could be reused for at least six cycles without losing activity. Moreover, chemoselective reduction of 3 nitrostyrene was achieved with high yield (80%–98%) of 3-aminostyrene in alcohol/water cosolvent. Overall, this work demonstrates a positive nanoconfinement effect of CNFs for developing stable and recyclable metal NP catalysts.