Abstract
The advancement of efficient, recyclable adsorbents for the economical capture of uranium from seawater is critical for the sustainable progression of nuclear energy. In this work, a unique aerogel composed of covalent organic frameworks (COF-TpTHA)/cellulose nanofibrils (CNF) was synthesized under mild conditions for uranium adsorption. TpTHA/CNF aerogel resolves challenges related to the formability of COF. CNF utilized as the matrix to encapsulate COF-TpTHA in order to improve the dispersion and reinforce the composite materials. The introduction of COF-TpTHA endows CNF aerogel with sufficient active groups for uranium adsorption. X-ray diffraction (XRD) characterization confirmed the successful incorporation of COF while maintaining the type I structure of cellulose. Fourier-transform infrared (FT-IR) spectroscopy further validated the presence of hydrogen bonding interactions between COF and cellulose. The results demonstrated the excellent adsorption efficiency of TpTHA/CNF aerogel towards U(VI), with a maximum adsorption capacity of 177.90 mg g‐1 (experiment) for U(VI). Meanwhile, TpTHA/CNF aerogel exhibited favorable adsorption selectivity and reusability. This cellulose-encapsulated COF approach offers a simple and promising method for uranium extraction from seawater, demonstrating its significant application potential.
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