Abstract
An experimental study was conducted to examine the effectiveness of sodium carbonate in alkali, surfactant and polymer combined slugs in recovering waterflood residual oil. The effects of sodium carbonate concentration on the slug viscosity, interfacial tension, and phase behavior were first examined. Core flood experiments were conducted with unfired linear Berea sandstone cores. The incremental oil recovery, oil cut, residual resistance factor, and chemical propagation were measured for each flood. A significant oil bank was formed for all combined slugs having sodium carbonate concentration ≥1 wt%. The incremental oil recovery, oil cut and the injectivity of the combined slugs greatly improved as sodium carbonate concentration was increased. The effect of sodium carbonate concentration on chemical propagation was dramatic for the synthetic surfactant; a slight delay in surfactant breakthrough and a much slower rate of surfactant propagation were observed at high sodium carbonate concentrations. The results obtained in the present study indicate that the residual oil was recovered by two mechanisms: low interfacial tension and wettability reversal. The former mechanism is dominant at sodium carbonate concentrations ≤1 wt%, whereas the latter plays an important role only at high sodium carbonate concentrations.
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