Recovery of Rare Earths and Major Metals from Bauxite Residue (Red Mud) by Alkali Roasting, Smelting, and Leaching

Abstract

Bauxite residue (red mud) with a high alumina content requires large amounts of fluxes during smelting, which increases the overall process cost, the energy consumption during smelting, and the acid consumption during slag leaching and decreases the throughput of bauxite residue in the smelting phase. Therefore, alumina was removed (or recovered) from bauxite residue by alkali roasting prior to smelting. The sample after alumina removal could be smelted at 1500 °C without the need of adding any flux to obtain a clear slag–metal separation. After smelting, the slag was leached with acids (HCl, H2SO4, or HNO3). The recovery yields of the rare-earth elements (REEs), except scandium, drastically decreased in the low-alumina slags, compared to the original bauxite residue. These poorer recovery yields are due to the formation of a perovskite (CaTiO3) phase, which binds REEs except scandium. CaTiO3 is a stable phase and does not dissolve in acids under normal conditions. Therefore, slag was quenched to suppress the CaTiO3 formation. The REEs and titanium could also be dissolved in acidic solutions at 25 °C by quenching the molten slag. Removal of alumina from bauxite residue by alkali roasting with sodium carbonate requires high temperatures (>900 °C). Therefore, sodium carbonate was replaced with sodium hydroxide to decrease the energy consumption by decreasing the roasting temperature (<500 °C).