Recovery of minority carrier lifetime in low-cost multicrystalline silicon

Abstract

Lifetime of minority carriers has been widely identified to be the key material parameter determining the conversion efficiency of pn-junction silicon solar cells. Impurities and defects in the silicon crystal lattice reduce the charge carrier lifetime and thus limit the performance of the solar cells. Removal of impurities by silicon material purification is often contradictory with low cost production of photovoltaic devices. In this paper, we present experimental results of an efficient gettering technique which can be applied to low cost processing of multicrystalline silicon solar cells without any additional process steps or compromises with optimal device design parameters. This technique is based on well-known phosphorous gettering. We have discovered that if the silicon wafers are kept in the furnace after the emitter diffusion at the 700°C, significant improvement in the lifetime will take place. At this temperature the properties of the pn-junction remain unaffected meanwhile many lifetime killers are still mobile. The time needed for this temperature program can be easily modified in order to respond to the material quality variations in substrates originating from different parts of multicrystalline ingot. Better control of lifetime can lead to higher degree of starting material utilization.