Recovery of Apatite from Magnetic Concentration Tailings by Flotation

Abstract

Iron concentration tailings contain many valuable minerals, including apatite, which is not currently being recovered despite its use to make fertilizers and chemicals. This article proposes a flotation circuit to recover apatite from tailings generated by mining in Chile, based on laboratory tests and using the “Split Factor” method. The iron tailings were characterized by granulometry, chemical and mineralogical analyses, zeta potential, and contact angle. The effect of the collector, frother, and dispersant dose, along with the number of flotation stages, on both the grade and recovery of P2O5 were studied. The results indicate that it is possible to produce concentrates with a P2O5 grade of 29.1% and 89.6% recovery in a flotation circuit that includes the rougher–scavenger–cleaner stages. To obtain these results, it is only necessary to condition the iron tailings with 400 gt−1 of Atrac-2600, 400 gt−1 of sodium silicate, 10 min of conditioning time, pH adjustment to 10, and a time for the rougher, cleaner, and scavenger stages set at 10, 7.6, and 6.8 min, respectively. A chemical interaction is suggested, where the collector is specifically adsorbed onto the apatite surface.