Recovering ammonium from real treated wastewater by zeolite packed columns: The effect of flow rate and particle diameter

Abstract

Nitrogen (N) recovery from wastewater is a desirable way to create a (N) neutral society in view of a circular economy approach. Nitrogen recovery from wastewater by employing adsorption columns filled with zeolite can be a very attractive solution. This study assessed the effect of influent flow rates (namely, 1.6 and 2.3 L h−1) and particle diameters (namely, 0.5–1.0 and 2.0–5.0 mm) of zeolite packed in columns on recovering NH4+ from real domestic treated wastewater (RDTWW). Findings revealed that maximum NH4+ recovery can be achieved by using zeolite with the smallest particle diameter (0.5–1.0 mm) and the highest influent flow rate (2.3 L h-1). The maximum NH4+ adsorption rate was 1.2, 21 and 9.8 mg NH4+ kg-1 h-1 after 205, 32 and 35 h of operation. NH4+ adsorption data were analysed by fitting them to both pseudo-first and pseudo-second order kinetic models. The former model best approximated NH4+ adsorption data. Such a result suggested that the amount of NH4+ adsorbed depended solely on the amount of NH4+ in contact with the zeolite surface. Results successfully established the application of zeolite-packed columns in removing NH4+ from real domestic treated wastewater and the effects of process parameters.