Recommended Collision Integrals for Transport Property Computations Part 1: Air Species

Abstract

Ar eview of the best-available data for calculating a complete set of binary collision integral data for the computation of the mixture transport properties (viscosity, thermal conductivity, and ordinary and thermal diffusion) of 13-species weakly ionized air is presented. Although the fidelity of the data varies, all collision integrals presented herein, except for electron-neutral interactions, are estimated to be accurate to within 25% over the temperature range of interest (300‐15,000 K) for reentry and laboratory plasmas. In addition, most of the dominant atom‐atom and atom‐ion interactions for dissociated weakly ionized air were derived from ab initio methods that are estimated to be accurate to within 10%. The accuracy and valid temperature range for electron-neutral interactions vary because of scarcity of the required cross-sectional data.