Abstract

AbstractThe kinetics of recombination reactions in the light of current theory, and a simplified “working” expression for the calculation of effective rate constants of atmospheric recombination reactions as a function of altitude are presented. An application of this expression to the effective atmospheric “fall‐off” behaviour of the reactions OH + NO2, OH + NO, OH + SO2, ClO + NO2 and HO2 + NO2 is given.

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