Abstract

AbstractThe simultaneous investigation of electroreflection (ER) and secondary radiation (SR) spectra of ZnxCd1−xSe solid solutions under off‐resonance (resonance) laser excitation at 5 to 300 K reveals the fine structure of the fundamental absorption edge which arises from the direct and indirect creation and annihilation of excitons of series Γ6–Γ8 or Γ7–Γ9 und Γ7–Γ7. The shape of the SR exciton line at low temperatures is determined by the exciton trapping processes at random potential fluctuations of composition. This statistic random potential manifests itself in a blue shift of the SR exciton line with the N2‐laser excitation. The behaviour of the SR exciton line at 77 K is strongly governed by the exciton annihilation processes with the simultaneous emission or absorption of LO phonons. A possible effect of extended and self‐trapped exciton states in SR spectra at high temperature is considered.

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