Abstract

Horizontal attenuation total reflection Fourier transformation infrared spectroscopy (HATR-FT-IR) studies on cuscutae semen and its confusable varieties Japanese dodder and sinapis semen combined with discrete wavelet transformation (DWT) and radial basis function (RBF) neural networks have been conducted in order to classify them. DWT is used to decompose the FT-IRs of cuscutae semen, Japanese dodder, and sinapis semen. Two main scales are selected as the feature extracting space in the DWT domain. According to the distribution of cuscutae semen, Japanese dodder, and sinapis semen's FT-IRs, three feature regions are determined at detail 3, and two feature regions are determined at detail 4 by selecting two scales in the DWT domain. Thus five feature parameters form the feature vector. The feature vector is input to the RBF neural networks to train so as to accurately classify the cuscutae semen, Japanese dodder, and sinapis semen. 120 sets of FT-IR data are used to train and test the proposed method, where 60 sets of data are used to train samples, and another 60 sets of FT-IR data are used to test samples. Experimental results show that the accurate recognition rate of cuscutae semen, Japanese dodder, and sinapis semen is average of 100.00%, 98.33%, and 100.00%, respectively, following the proposed method.

Highlights

  • At present in the medical field, the biggest achievement of the human beings is western medicine and traditional Chinese medicine (TCM)

  • Cuscutae semen is a kind of TCM, which has been known for the treatment of diseases for a long time

  • The results showed that the artificial neural network can be better used for juice brix and the rapid determination of the optical rotation [14]

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Summary

Introduction

At present in the medical field, the biggest achievement of the human beings is western medicine and traditional Chinese medicine (TCM). How to make use of the large amount of data of absorption spectra from complex system for fast qualitative and quantitative analysis effectively and make the information that is buried in the FT-IR overlapping bands and the difference that existed in the infrared absorptions spectra be displayed visually for the identification of those spectra which are similar and Journal of Analytical Methods in Chemistry complicated have been a goal of analytical chemists [5,6,7]. Wavelet transformation is a more effective signal processing method than Fourier transform, and the transformed results (wavelet factor) of discrete wavelet transform (DWT) contain more valuable information, which is a relatively effective analysis method in chemometrics. Discrete stationary wavelet transformation (DSWT) and probability neural networks have been successfully applied to FT-IR analysis, but few studies have been reported in the FT-IRDWT-radial basis function (RBF) neural network application to recognition TCM [6, 8]. HATR-FT-IR spectroscopy combined with DWT and RBF neural network discrimination method was proposed for the rapid and simple classification of cuscutae semen, Japanese dodder, and sinapis semen making a difficult distinction among them from morphology in this study

Experimental
Results and Discussion
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