Abstract
Publisher Summary Fluorophosphines are tervalent phosphorus compounds containing phosphorus-fluorine bonds and they often show markedly different chemical behavior compared with other halogenophosphines. This article is mainly concerned with recent advances in the chemistry of derivatives of PF, of the type PF3-nXa, with particular reference to (a) synthesis of new structural types, ( b ) the role of fluorophosphines as ligands, particularly, in transition metal complexes, and ( c ) nuclear magnetic resonance (NMR) studies.Since fluorophosphines form part of a general review of phosphorus fluorides (282), and there is an excellent account of transition metaltrifluorophosphine complexes, the present article is not intended to be comprehensive, but rather to highlight some of the more recent developments in this expanding area of inorganic chemistry.
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